Portal del Investigador
Influence of the comonomer content on the thermal and dynamic mechanical properties of metallocene ethylene/1-octene copolymers
Keywords: catalysis, spectroscopy, crystal, polymers, thermodynamics, chromatography, polymerization, crystallization, structure, gel, copolymers, metallocene, ethylene, polyethylenes, monomer, permeation, monomers, article, raman, organic, dynamic, thermodynamic, mechanical, properties, differential, calorimetry, scanning, derivative, Octene
Abstract
Studies of ethylene/1-octene copolymers prepared by a metallocene catalyst were carried out through dynamic-mechanical experiments (DMTA), differential scanning calorimetry (DSC), Raman spectroscopy and gel permeation chromatography (GPC). The influence of comonomer content on the ethylene/1-octene properties, specially those related to the dynamic- mechanical behaviour were studied. It was observed that the intensity of the ?-transition increases as the comonomer content increases and decreases crystallinity. Studies of ethylene/1-octene copolymers prepared by a metallocene catalyst were carried out through dynamic-mechanical experiments (DMTA), differential scanning calorimetry (DSC), Raman spectroscopy and gel permeation chromatography (GPC). The influence of comonomer content on the ethylene/1-octene properties, specially those related to the dynamic-mechanical behaviour were studied. It was observed that the intensity of the ?-transition increases as the comonomer content increases and decreases crystallinity.
Más información
| Título de la Revista: | POLYMER |
| Volumen: | 40 |
| Número: | 20 |
| Editorial: | ELSEVIER SCI LTD |
| Fecha de publicación: | 1999 |
| Página de inicio: | 5489 |
| Página final: | 5495 |
| URL: | http://www.scopus.com/inward/record.url?eid=2-s2.0-0032769553&partnerID=q2rCbXpz |