Article SCOPUS
ARKIVOC  (2003)

Regioselective oxidative fragmentation of drimanic terpene alcohols: Ashort, easy and efficient access to natural and synthetic 11-nordrimaneterpenederivatives

Cuellar M.A.; Moreno L.E.; Preite M.D.

Keywords: oxidation, fragmentation, aerobic, metabolism, stereochemistry, drug, article, chromium, analysis, drimenol, 7, 1, 3, derivative, Reaction, 2, 1h, unclassified, oxo, 4h, one, terpene, diol, naphthalen, 11,12, Pyridinium, trimethyl, tetramethyl, carbaldehyde, hexahydro, 2,5,5,8a, 4a,5,6,7,8,8a, 3,4a,8,8, 5,5,8a, 1,4,4a,5,6,7,8,8a, octahydronaphthalene, 3,4,4a,5,6,7,8,8a, drimene, chlorochromate

Abstract

Using selective Cr(VI) oxidations with Jones reagent and PCC, a regioselective and direct access to different oxygenated 11-nordrimane skeletons was achieved, in good overall yield, starting from naturally occurring drimane terpenes.

Más información

Título según SCOPUS: Regioselective oxidative fragmentation of drimanic terpene alcohols: Ashort, easy and efficient access to natural and synthetic 11-nordrimaneterpenederivatives
Título de la Revista: ARKIVOC
Volumen: 2003
Número: 10
Editorial: ARKAT USA INC
Fecha de publicación: 2003
Página de inicio: 169
Página final: 177
Idioma: English
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-3242666056&partnerID=q2rCbXpz
Notas: SCOPUS