Abstract

Dibenzothiophene (DBT) hydrodesulphurization (HDS) reaction at 3 MPa and 325-375 °C on Mo/?-Al 2O 3 single-bed and Me/?-Al 2O 3//SiO 2//Mo/?-Al 2O 3 (Me = Co or Ni) double-bed catalysts were investigated. Results indicate that ratio cyclohexylbenzene (CHB)/biphenyl (BP) or selectivity is higher when using double-beds rather than a single-bed. Synergy in dibenzothiophene hydrodesulphurization on Co//Mo and Ni//Mo double-beds is also detected. Changes in selectivity and conversion are attributed to the action of spillover hydrogen (Hso) formed in the first bed that reaches the second bed. © 2006 Elsevier B.V. All rights reserved.