Biosorption of cadmium with brown macroalgae

Gutiérrez, Claudia; Hansen, Henrik K.; Hernández, Piroska; Pinilla, Carolina

Keywords: cadmium uptake, lessonia nigrescens, adsorption isotherm, sorption kinetics, Durvillaea antarctica

Abstract

Sorption experiments for cadmium removal using two brown macroalgae Lessonia nigrescens and Durvillaea antarctica were carried out. Although both types of algae were capable of retaining cadmium, differences in their performance were observed. The optimum pH was 3.7 ± 0.2, and to achieve the equilibrium, 5 days of contact time were necessary for both biosorbents. The maximum experimental uptake obtained was similar for the two biosorbents: 95.3 mg Cd g-1 by D. antarctica and 109.5 mg Cd g-1 by L. nigrescens. The Langmuir model described the equilibrium sorption isotherms very well for both biosorbents and the Lagergren pseudo primer order model described the sorption kinetics for L. nigrescens satisfactorily and the Ho and Mckay pseudo second order model for D. antarctica. It was found that cadmium uptake by D. antarctica was faster than by L. nigrescens.

Más información

Título de la Revista: CHEMOSPHERE
Volumen: 138
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2015
Página de inicio: 164
Página final: 169