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EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES
Abstract
"In the series of organometallic complexes N3P2(X)5P-SPACER-MLn X= Cl and OR, MLn= organometallic fragment , the delta31 P-NMR coordination chemical shift parameter correlates with the length of the spacer, decaying exponentially with the length of it. The bridging spacers behave like a ""molecular wire"" showing dependence of the charge transfer with the distance, similar to electron transfer in donor-acceptor systems. Extended H
Más información
| Título según WOS: | Exponential decay of a charge transfer induced by coordination in organometallic complexes |
| Título según SCOPUS: | Exponential decay of a charge transfer induced by coordination in organometallic complexes |
| Título según SCIELO: | EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES |
| Título de la Revista: | BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA |
| Volumen: | 46 |
| Número: | 3 |
| Editorial: | Sociedad Chilena de Química |
| Fecha de publicación: | 2001 |
| Página de inicio: | 293 |
| Página final: | 299 |
| Idioma: | English |
| DOI: |
10.4067/S0366-16442001000300009 |
| Notas: | ISI, SCIELO, SCOPUS |