Synthesis of (+)-cyclozonarone and the absolute configuration of naturally occurring (-)-cyclozonarone

Cortes, M; Valderrama, JA; Cuellar, M; Armstrong, V; Preite, M

Abstract

Synthesis of (+)-cyclozonarone (1) has been achieved using (-)-polygodial (3) as chiral starting material. The absolute configuration of naturally occurring (-)-cyclozonarone was established as 5R,10R by comparison of spectral data and optical rotation with those of (+)-cyclozonarone.

Más información

Título según WOS: Synthesis of (+)-cyclozonarone and the absolute configuration of naturally occurring (-)-cyclozonarone
Título según SCOPUS: Synthesis of (+)-cyclozonarone and the absolute configuration of naturally occurring (-)-cyclozonarone
Título de la Revista: JOURNAL OF NATURAL PRODUCTS
Volumen: 64
Número: 3
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2001
Página de inicio: 348
Página final: 349
Idioma: English
URL: http://pubs.acs.org/doi/abs/10.1021/np0004146
DOI:

10.1021/np0004146

Notas: ISI, SCOPUS