Article ISI SCOPUS
ORGANIC LETTERS  (2002)

Geometry and halogen regiochemistry determination of vicinal vinyl dihalides by H-1 and C-13 NMR. Application to the structure elucidation of prefuroplocamioid, an unusual marine monoterpene

Diaz-Marrero, AR; Cueto M.; Dorta, E; Rovirosa, J; San Martin, A; Darias J.

Abstract

(equation presented) Empirical rules based on 13C and 1H NMR spectroscopy to determine the regiochemistry and geometry of the 1,2-bromochloro vinyl portion of naturally occurring or synthetic compounds containing this functionality are proposed. The key feature of the method comes from the comparison of the spectral data of the new monoterpene metabolite, prefuroplocamioid, isolated from Plocamium cartilagineum, with those of other marine monoterpenes, as well as with some model compounds found in the literature.

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Título según WOS: Geometry and halogen regiochemistry determination of vicinal vinyl dihalides by H-1 and C-13 NMR. Application to the structure elucidation of prefuroplocamioid, an unusual marine monoterpene
Título según SCOPUS: Geometry and halogen regiochemistry determination of vicinal vinyl dihalides by 1H and 13C NMR. Application to the structure elucidation of prefuroplocamioid, an unusual marine monoterpene
Título de la Revista: ORGANIC LETTERS
Volumen: 4
Número: 17
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2002
Página de inicio: 2949
Página final: 2952
Idioma: English
URL: http://pubs.acs.org/doi/abs/10.1021/ol026353f
DOI:

10.1021/ol026353f
Notas: ISI, SCOPUS