Accelerating Copper Leaching from Sulfide Ores in Acid-Nitrate-Chloride Media Using Agglomeration and Curing as Pretreatment

Hernández, Pía C.; Dupont, Junior; Herreros, Osvaldo O.; Jimenez, Yecid P.; Torres, Cynthia M.

Abstract

This work investigates the effect of an agglomeration and curing pretreatment on leaching of a copper sulfide ore, mainly chalcopyrite, using mini-columns in acid-nitrate-chloride media. Ten pretreatment tests were conducted to evaluate different variables, namely the addition of nitrate as NaNO3 (11.7 and 23.3 kg/ton), chloride as NaCl (2.1 and 19.8 kg/ton), curing time (20 and 30 days) and repose temperature (25 and 45 degrees C). The optimum copper extraction of 58.6% was achieved with the addition of 23.3 kg of NaNO3/ton, 19.8 kg of NaCl/ton, and after 30 days of curing at 45 degrees C. Under these pretreatment conditions, three samples of ore were leached in mini-columns. The studied parameters were temperature (25 and 45 degrees C) and chloride concentration (20 and 40 g/L). The optimum copper extraction of 63.9% was obtained in the mini-column leaching test at 25 degrees C, with the use of 20 g/L of chloride. A higher temperature (45 degrees C) and a higher chloride concentration (40 g/L) negatively affected the extraction. The pretreatment stage had favorable effects, in terms of accelerating copper dissolution and improving leaching of copper sulfide ore in acid-nitrate-chloride media. Waste salts from caliche industry and waste brine from reverse osmosis can be used for providing the nitrate and chloride media.

Más información

Título según WOS: Accelerating Copper Leaching from Sulfide Ores in Acid-Nitrate-Chloride Media Using Agglomeration and Curing as Pretreatment
Título según SCOPUS: Accelerating copper leaching from sulfide ores in acid-nitrate-chloride media using agglomeration and curing as pretreatment
Título de la Revista: Minerals
Volumen: 9
Número: 4
Editorial: MDPI
Fecha de publicación: 2019
Idioma: English
DOI:

10.3390/min9040250

Notas: ISI, SCOPUS - WOS