The origin of the second relaxation process in the [Mn(12)O(12)(O(2)CR)(16)(H(2)O)(4)] single-molecule magnets: 'Jahn-Teller isomerism' in the [Mn(12)O(12)] core

Sun, ZM; Ruiz, D; Dilley, NR; Soler, M; Ribas, J; Folting, K; Maple, MB; Christou, G; Hendrickson, DN

Abstract

The origin of the second, faster relaxation process in Mn(12) molecules has been identified as a different relative orientation of the Jahn-Teller elongation axes of the Mn(III) ions, which we have termed 'Jahn-Teller isomerism'.

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Título según WOS: ID WOS:000082817400026 Not found in local WOS DB
Título de la Revista: CHEMICAL COMMUNICATIONS
Número: 19
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 1999
Página de inicio: 1973
Página final: 1974
DOI:

10.1039/a906451f

Notas: ISI