Article ISI SCOPUS
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS  (2003)

Two isomorphous imidazole (Him) complexes: [MCl2(Him)(2)(H2O)(2)] (M = Co and Ni)

Atria, AM; Cortes P.; Garland, MT; Baggio R.

Abstract

The structures of aquadichlorobis(1H-imidazole)cobalt(II), [CoCl 2(Him)2(H2O)2] (Him is 1H-imidazole, C3H4N2), (I), and aquadichlorobis(1H-imidazole)nickel(II), [NiCl2(Him) 2(H2O)2], (II), are isomorphous and consist of monomers with inversion symmetry. The three monodentate ligands (imidazole, chlorine and aqua), together with their symmetry equivalents, define almost perfect octahedra. Hydrogen-bonding interactions via the imidazole and aqua H atoms lead to a three-dimensional network.

Más información

Título según WOS: Two isomorphous imidazole (Him) complexes: [MCl2(Him)(2)(H2O)(2)] (M = Co and Ni)
Título según SCOPUS: Two isomorphous imidazole (Him) complexes: [MCI2(Him) 2(H2O)2] (M = Co and Ni)
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volumen: 59
Número: 10
Editorial: WILEY-BLACKWELL PUBLISHING, INC
Fecha de publicación: 2003
Página de inicio: M396
Página final: M398
Idioma: English
DOI:

10.1107/S0108270103018080
Notas: ISI, SCOPUS