CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
Abstract
In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H center dot center dot center dot Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H center dot center dot center dot F, H center dot center dot center dot pi and H center dot center dot center dot Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.
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Título según WOS: | CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE |
Título según SCOPUS: | Crystal structure and Hirshfeld surface analysis of (E)-5-phenyl-3-((4-(trifluoromethyl)benzylidene)amino)thiazolidin-2-iminium bromide |
Título según SCIELO: | CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE |
Título de la Revista: | Journal of the Chilean Chemical Society |
Volumen: | 64 |
Número: | 2 |
Editorial: | SOC CHILENA QUIMICA |
Fecha de publicación: | 2019 |
Página de inicio: | 4441 |
Página final: | 4447 |
Idioma: | English |
DOI: |
10.4067/S0717-97072019000204441 |
Notas: | ISI, SCIELO, SCOPUS |