CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

Abel M. Maharramov; Gulnara SH. Duruskari; Gunay Z. Mammadova; Ali N. Khalilov; Javahir M. Aslanova; Jonathan Cisterna; Alejandro Cárdenas; Iván Brito

Abstract

In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H center dot center dot center dot Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H center dot center dot center dot F, H center dot center dot center dot pi and H center dot center dot center dot Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.

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Título según WOS: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
Título según SCOPUS: Crystal structure and Hirshfeld surface analysis of (E)-5-phenyl-3-((4-(trifluoromethyl)benzylidene)amino)thiazolidin-2-iminium bromide
Título según SCIELO: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
Título de la Revista: Journal of the Chilean Chemical Society
Volumen: 64
Número: 2
Editorial: SOC CHILENA QUIMICA
Fecha de publicación: 2019
Página de inicio: 4441
Página final: 4447
Idioma: English
DOI:

10.4067/S0717-97072019000204441

Notas: ISI, SCIELO, SCOPUS