OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND

Calero, R; Vega A.; Garcia, AM; Spodine, E.; Manzur, J.

Abstract

The oxidation product of the binuclear copper (I) complex Cu2L(ClO4)2 (L = N,N'-bis-(6-methyl-2-pyridil) (2'-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, [Cu2L(Me-O)2](ClO4 )2, the metal centres are bridged by two methoxide groups, and the oxygenation of the xylyl spacer of the hexadentate ligand is not observed. The copper(I) complex was found to be a catalyst for the oxidation of 3,5-ditertbutylcatechol to 3,5-ditertbutyl-o-benzoquinone by molecular oxygen

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Título según WOS: Oxidation and catalytic properties of a binuclear copper(I) complex with a meta-xylyl spacer ligand.
Título según SCIELO: OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
Título de la Revista: Journal of the Chilean Chemical Society
Volumen: 48
Número: 2
Editorial: SOC CHILENA QUIMICA
Fecha de publicación: 2003
Página de inicio: 85
Página final: 88
Idioma: English
DOI:

10.4067/S0717-97072003000200015

Notas: ISI, SCIELO