Communication: Vibrational relaxation of CO((1)Sigma) in collision with Ar(S-1) at temperatures relevant to the hypersonic flight regime

Denis-Alpizar, Otoniel; Bemish, Raymond J.; Meuwly, Markus

Abstract

Vibrational energy relaxation (VER) of diatomics following collisions with the surrounding medium is an important elementary process for modeling high-temperature gas flow. VER is characterized by two parameters: the vibrational relaxation time tau(vib) and the state relaxation rates. Here the vibrational relaxation of CO(v = 0 - v = 1) in Ar is considered for validating a computational approach to determine the vibrational relaxation time parameter (p tau(vib)) using an accurate, fully dimensional potential energy surface. For lower temperatures, comparison with experimental data shows very good agreement whereas at higher temperatures (up to 25 000 K), comparisons with an empirically modified model due to Park confirm its validity for CO in Ar. Additionally, the calculations provide insight into the importance of Delta v > 1 transitions that are ignored in typical applications of the Landau-Teller framework. Published by AIP Publishing.

Más información

Título según WOS: ID WOS:000397313600002 Not found in local WOS DB
Título de la Revista: JOURNAL OF CHEMICAL PHYSICS
Volumen: 146
Número: 11
Editorial: AIP Publishing
Fecha de publicación: 2017
DOI:

10.1063/1.4978498

Notas: ISI