(2S,R-S)-6-Phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol
Abstract
The molecule of the title compound, C19H20O 2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulflnyl S atom. The molecule displays a V-shape in the solid state. The dihedral angle defined by the least-squares planes of the aromatic rings is 72.9 (1)°. The packing pattern exhibits the following intermolecular hydrogen bonds: one O-H⋯O [H⋯O = 1.98 Å, O⋯O = 2.785 (4) Å and O-H⋯O = 166°] and two C-H⋯O [H⋯O = 2.58 and 2.60 Å, C⋯O = 3.527(5) and 3.347 (5) Å, and C-H⋯O = 164 and 134°]. These define a chain along b. © 2006 International Union of Crystallography.
Más información
| Título según WOS: | (2S,R-S)-6-Phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol |
| Título según SCOPUS: | (2S,RS)-6-phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol |
| Título de la Revista: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS |
| Volumen: | 62 |
| Número: | 10 |
| Editorial: | WILEY-BLACKWELL PUBLISHING, INC |
| Fecha de publicación: | 2006 |
| Página de inicio: | O631 |
| Página final: | O632 |
| Idioma: | English |
| URL: | http://scripts.iucr.org/cgi-bin/paper?S0108270106036171 |
| DOI: |
10.1107/S0108270106036171 |
| Notas: | ISI, SCOPUS |