Synthesis, Characterization and Performance of Nanostructured 2D Turbostratic Graphite Particles Derived from the Solid-State Reaction Between Carbides

Araya, Nicolás; Neves, Guilherme; Binder, Cristiano; Klein, Aloisio N.; Biasoli de Mello, José Daniel

Abstract

In this work, a novel synthesis method of nanostructured carbon derived from carbides was developed. From phase diagram calculations, the boron and chromium carbides system was defined. The process developed consisted of the solid-state reaction between the carbides followed by a stage of chemical dissolution using hydrochloric acid. From this process, it was possible to recover practically all the carbon present in the system (∼15 wt.%) and a mechanism for the formation of nanostructure carbon during the reaction was proposed. The carbon produced by this method presented a 2D nanostructured turbostratic structure. As a result, they were able to reduce friction and wear of metal-metal pairs under dry and oil-lubricated sliding conditions. These particles also showed excellent dispersibility in the lubricant oil, opening a wide range of applications for this material as a lubricant additive.

Más información

Título de la Revista: MATERIALS RESEARCH BULLETIN
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2022
URL: 10.1016/j.materresbull.2022.111826
Notas: WOS