Nanostructured electrochemical sensor applied to the electrocoagulation of arsenite in WWTP effluent

Pina, Samuel; Sandoval, A. Miguel; Jara-Ulloa, Paola; Contreras, David; Hassan, Natalia; Coreno, Oscar; Salazar, Ricardo

Abstract

A sensitive electroanalytical method for the determination of arsenite, based on a heterostructure of aminated multiwalled carbon nanotubes and gold nanoparticles, was applied in an electrocoagulation (EC) treatment for the elimination of arsenite. A sensitive quantitative response was obtained in the determination of As3+ in a secondary effluent from a wastewater treatment plant from Santiago (Chile). The preconcentration stage was optimized through a Central Composite Face design, and the most sensitive peak current was obtained at 200 s and -600 mV of time and accumulation potential, respectively, after a differential pulse voltammetry sweep. Electroanalytical determination was possible in an interval between 42.89 and 170.00 mu g L-1 with a detection limit of 0.39 mu g L-1, obtaining recoveries over 99.1%. The developed method was successfully applied in an electrocoagulation treatment to remove 250 mu g L-1 of arsenite from a polluted effluent in a batch system. Complete arsenite removal was achieved using a steel EC system with a current density of 6.0 mA cm(-2) in less than 3 min of treatment.

Más información

Título según WOS: Nanostructured electrochemical sensor applied to the electrocoagulation of arsenite in WWTP effluent
Título de la Revista: CHEMOSPHERE
Volumen: 306
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2022
DOI:

10.1016/j.chemosphere.2022.135530

Notas: ISI