Abstract

We found that the force between glass surfaces measured with an atomic force microscope (AFM) has universal character in the short range, less than ∼1 nm or about 3-4 water molecules, independent of solution conditions, that is, electrolyte ion size, charge and concentration and pH. Our results suggest that the excess DLVO force, obtained by subtracting the DLVO theory with a charge regulation model from the AFM force data, essentially does not change with the electrolytes Na, Ca, and Al, in the range of concentration from 10 -6 to 10-2 M and the range of pH from 3.1 to 7.9. Single force curves for a glass-silica system in a 10-4 M aqueous NaCl solution at pH ∼5.1 show oscillations with a period of about 0.25 nm, roughly the diameter of a water molecule. We postulate that the excess force between glass surfaces arises from a surface-induced solvent effect, from the creation of a hydrogen-bonding network at the surface level, rather than from a solvent-induced surface steric hindrance. © 2008 American Chemical Society.