Enhanced Photocatalytic Degradation of ZnTiO3/Polycarbazole (PCz) Composite Towards Toxic Azo Dye

Kamaraj, Jeffrey Joseph John Jeya; Annamalai, Padmanaban; Tamil, Lawrence Daniel Stephen; Muthu, Senthil Pandian; Perumalsamy, Ramasamy; Valdes, Hector

Abstract

The ZnTiO3 material was synthesized by sol-gel method with the assistance of ethanol as solvent. The oxidative polymerization method was used to synthesize polycarbazole (PCz). The ball milling technique was employed to synthesize the mechanically composited nanoparticles-ZnTiO3/PCz nanocomposite. The synthesized composites were analysed using powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectrum (XPS), UV-Vis absorption spectrum (UV-Vis), scanning electron microscope (SEM), and high-resolution transmission electron microscope (HRTEM). The degradation of crystal violet (CV) in water under visible-light irradiation was used to assess the photocatalytic behaviour of the synthesized catalyst. The result shows that the ZnTiO3/PCz composites exhibit greater photocatalytic activity than other materials. Polycarbazole in composite material acts as an electron reservoir, actively trapping the photogenerated electrons which considerably lowers the probability of recombination and increases the degrading effect of the catalyst.

Más información

Título según WOS: ID WOS:000912234600005 Not found in local WOS DB
Título de la Revista: ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING
Volumen: 48
Número: 6
Editorial: SPRINGER HEIDELBERG
Fecha de publicación: 2023
Página de inicio: 8143
Página final: 8151
DOI:

10.1007/s13369-022-07570-2

Notas: ISI