Electrical Characterization of Hydrothermally Synthesized Manganese Dioxide Nanowires with Regard to NO2 Adsorption/Desorption Thermodynamics

Smisitel, Petr; Simunkova, Helena; Claros, Martha; Hubalek, Jaromir

Keywords: nanowires, nitrogen dioxide, manganese dioxide, gas sensing, ion mobility, Arrhenius plot, defect structure, variable oxidation state, structural instability

Abstract

Self-assembled MnO2 nanowires were hydrothermally synthesized and electrically characterized under different conditions. The nanowires were approximately 3–10 µm long and about 20–100 nm in diameter. Single nanowires were aligned perpendicularly across two parallel gold electrode transducers by means of the dielectrophoresis (DEP) technique. Resistivity changes in synthetic air, nitrogen, and NO2 were tested in a range from 100 °C up to 300 °C. The resistivity changes were observed to account for the oxygen reduction on the NWs’ surface as the electrons were moving from the NWs to the oxygen. The resistivity was explored through a constant current arrangement test. Based on the resistivity changes, electrical properties, such as activation energy and type of semiconductor, were estimated. © 2023 by the authors.

Más información

Título según SCOPUS: Electrical Characterization of Hydrothermally Synthesized Manganese Dioxide Nanowires with Regard to NO2 Adsorption/Desorption Thermodynamics †
Título de la Revista: Engineering Proceedings
Volumen: 48
Número: 1
Editorial: Multidisciplinary Digital Publishing Institute (MDPI)
Fecha de publicación: 2023
Idioma: English
URL: https://www.sciencedirect.com/science/article/pii/S2352940723001713
DOI:

10.3390/CSAC2023-14883

Notas: SCOPUS