Multifunctional Dy2NiMnO6/Reduced Graphene Oxide Nanocomposites and Their Catalytic, Electromagnetic Shielding, and Electrochemical Properties

Sahoo, Bibhuti Bhusan; Sahoo, Prasanta Kumar; Bhaviripudi, Vijayabhaskara Rao; Sahu, Krushna Chandra; Tripathi, Abhishek; Sahoo, Naresh Kumar; Aepuru, Radhamanohar; Gaikwad, Vishwajit M.; Sahoo, Srikant; Satpati, Ashis Kumar; Lee, Chuan-Pei

Abstract

Multifunctional nanocomposites have shown great interest in clean energy systems and environmental applications in recent years. Herein, we first reported the synthesis of Dy2NiMnO6 (DNMO)/reduced graphene oxide (rGO) nanocomposites utilizing a hybrid approach involving sol-gel and solvothermal processes. Subsequently, we investigated these nanocomposites for their applications in catalysis, electromagnetic interference shielding, and supercapacitors. A morphological study suggests spherical-shaped DNMO nanoparticles of an average size of 382 nm that are uniformly distributed throughout the surface without any agglomeration. The as-prepared nanocomposites were used as catalysts to investigate the catalytic reduction of 4-nitrophenol in the presence of NaBH4. DNMO/rGO nanocomposites demonstrate superior catalytic activity when compared with bare DNMO, with the rate of reduction being influenced by the composition of the DNMO/rGO nanocomposites. In addition, novel multifunctional DNMO/rGO was incorporated into polyvinylidene difluoride (PVDF) to develop a flexible nanocomposite for electromagnetic shielding applications and exhibited a shielding effectiveness of 6 dB with 75% attenuation at a frequency of 8.5 GHz compared to bare PVDF and PVDF-DNMO nanocomposite. Furthermore, the electrochemical performance of DNMO/rGO nanocomposites was investigated as an electrode material for supercapacitors, exhibiting the highest specific capacitance of 260 F/g at 1 A/g. These findings provide valuable insights into the design of DNMO/rGO nanocomposites with remarkable performance in sustainable energy and environmental applications.

Más información

Título según WOS: Multifunctional Dy2NiMnO6/Reduced Graphene Oxide Nanocomposites and Their Catalytic, Electromagnetic Shielding, and Electrochemical Properties
Título de la Revista: ACS OMEGA
Volumen: 9
Número: 4
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2024
Página de inicio: 4600
Página final: 4612
DOI:

10.1021/acsomega.3c07759

Notas: ISI