Harnessing non-edible Quercus incana seeds for sustainable and clean biodiesel production using seed-derived green Al2O3 nanocatalyst

Munir, Mumna; Ahmad, Mushtaq; Alsahli, Abdulaziz Abdullah; Zhang, Lixin; Islamov, Sokhib; Sultana, Shazia; Mussagy, Cassamo Ussemane; Mustafa, Ahmad; Munir, Mamoona; Chaudhry, Bisha; Hamayun, Maria; Khawaja, Sarwar

Abstract

The challenges of resource scarcity and waste deposition have increased raw material costs and imposed stricter waste management regulations. This study presents the first attempt to utilize high oil-yielding Quercus incana seeds (55.77 wt%, 0.28 % FFA) as a novel waste feedstock for synthesizing a bio-fabricated Al2O3 nanocatalyst and its application in producing high-quality biodiesel. A maximum biodiesel yield of 97.6 % was achieved under optimal conditions, including a 1:9 oil-to-methanol ratio, a 120-minute reaction time at 70 degrees C, and 0.25 % catalyst concentration. The formation of biodiesel was confirmed through various analytical techniques, such as 1 H- and 13 C NMR, FTIR, and GC-MS. Additionally, the physicochemical properties of the biodiesel, including sulfur content (0.00047 wt%), TAC (0.20 mg KOH/g), cloud point, and pour point (-11 degrees C), were analyzed and compared to international biodiesel standards to ensure its stability, sustainability, and eco-friendliness. The production of biodiesel from Quercus incana, a non-edible, uncultivated waste feedstock, supports a greener revolution and a net-zero carbon society. It also promotes smarter waste management practices globally.

Más información

Título según WOS: ID WOS:001339923600001 Not found in local WOS DB
Título de la Revista: SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
Volumen: 72
Editorial: Elsevier
Fecha de publicación: 2024
DOI:

10.1016/j.seta.2024.104025

Notas: ISI