Abstract

This research explores elastomeric nanocomposites consisting of ethylene propylene diene monomer rubber/natural rubber (NR/EPDM) in various ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 phr). The study incorporates EPDM grafted maleic anhydride (EPDM-g-MAH) as a compatibilizer, along with different quantities of Ti3C2TX reinforcement (1, 3, 5, 7, and 10 phr). To assess the dispersion and morphology of Ti?C?TX reinforcement in the NR/EPDM matrix, this study employed transmission electron microscopy (TEM) and scanning electron microscopy (SEM). These analyses revealed that, in the presence of EPDM-g-MAH, higher Ti3C2TX concentrations led to rougher fracture surfaces in the samples, indicating the excellent dispersion of Ti3C2TX in the NR/EPDM matrix. The investigation of mechanical and rheological properties demonstrated significant enhancements with increasing Ti3C2TX concentration in conjunction with EPDM-g-MAH. The study further explored the relationships between the nanocomposites' morphology and their theoretical and experimental mechanical properties through Mori-Tanaka analysis and dynamic mechanical thermal analysis (DMTA), respectively. These analyses revealed a strong correlation between theory and experimentation. The mechanical behavior of the composites exhibited notable improvements in tensile strength, hardness, modulus, elongation at break, and fatigue strength with the addition of Ti3C2TX, particularly in the presence of EPDM-g-MAH. Ultimately, our findings highlight the compatibility between theoretical analyses and experimental outcomes, validating the efficacy of Ti3C2TX incorporation in enhancing the properties of nanocomposites. © 2025 Elsevier B.V.