Anti-electrostatic cation??-hole and cation?lp-hole interactions are stabilized via collective interactions

Pino-Rios; R.; Báez-Grez; R.; Foroutan-Nejad; C.

Abstract

Collective interactions are a novel type of bond between metals and AX3 fragments with an electropositive central atom, A, and electronegative X substituents. Here, using electrostatic potential maps and state-of-the-art bonding analysis tools we have shown that collective interactions are anti-electrostatic cation??-Hole or cation?lp-Hole interactions. © 2024 The Royal Society of Chemistry.

Más información

Título según WOS: Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized via collective interactions
Título según SCOPUS: Anti-electrostatic cation??-hole and cation?lp-hole interactions are stabilized via collective interactions
Título de la Revista: Chemical Communications
Volumen: 60
Número: 4
Editorial: Royal Society of Chemistry
Fecha de publicación: 2023
Página de inicio: 400
Página final: 403
Idioma: English
DOI:

10.1039/d3cc05451a

Notas: ISI, SCOPUS