Article SCOPUS
Journal of Organic Chemistry  (2021)

Cucurbit[7]uril as a Supramolecular Catalyst in Base-Catalyzed Reactions. Experimental and Theoretical Studies on Carbonate and Thiocarbonate Hydrolysis Reactions

Fierro A.; García-Río L.; Arancibia-Opazo S.; Alcázar J.J.; Santos J.G.; Aliaga M.E.

Abstract

Cucurbit[7]uril (CB7) catalyzes the hydrolysis reaction of bis(4-nitrophenyl)carbonate (1) but inhibits that of bis(4-nitrophenyl)thiocarbonate (2). Two relevant CB7 effects are proposed, a base-catalyst mediated by the CB7 portal and an inhibitory role attributed to the lower interaction of the thiocarbonyl group with the solvent in the host cavity, respectively.

Más información

Título según SCOPUS: Cucurbit[7]uril as a Supramolecular Catalyst in Base-Catalyzed Reactions. Experimental and Theoretical Studies on Carbonate and Thiocarbonate Hydrolysis Reactions
Título de la Revista: Journal of Organic Chemistry
Volumen: 86
Número: 2
Editorial: American Chemical Society
Fecha de publicación: 2021
Página final: 2027
Idioma: English
DOI:

10.1021/acs.joc.0c02728
Notas: SCOPUS