Bis(?5-hydropentalenyl)iron

Molins, E; Maniukiewicz W.; Miravitlles C.; Mas, M.; ManrÍquez J.M.; Chavez, I; Oelckers, B; Farran J.; Brianso J.L.

Keywords: iron, ligands, crystal, structure, bonds, molecular, organometallics, staphylococcus, conformations, pentalene, phage, compounds, chemical, Aromatic, atomic, 3A

Abstract

In the structure of bis[(3a,4,5,6,6a-?)-1-hydropentalenyl]iron, [Fe(C8H7)2], the two pentalene ligands are parallel. The molecules are packed in chains along the a axis and there are no significant intermolecular interactions. The compound shows disorder at the iron position with a 93.3% major and a 6.7% minor component. The structure of the predominant component has been determined. In addition, the double bond in one pentalene ligand is disordered. This confirms the results of a previous spectroscopic 1H NMR study [Katz & Rosenberger (1963). J. Am. Chem. Soc. 85, 2030-2031].

Más información

Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volumen: 52
Número: 10
Editorial: WILEY-BLACKWELL PUBLISHING, INC
Fecha de publicación: 1996
Página de inicio: 2414
Página final: 2416
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-3643079654&partnerID=q2rCbXpz