Irreversible electrostatic deposition of CdTe quantum dots on glassy carbon electrodes from colloidal solutions

Navarrete E.; Rojas V.; Romero M.; Román J.; Cáceres G.; Henríquez R.; Grez P.; Schrebler R.; Herrera F.; Muñoz E.C.

Keywords: Cadmium telluride; Electrostatic deposition; Glassy carbon; Quantum dots; Scanning electrochemical microscopy

Abstract

Cadmium telluride quantum dots (CdTe-QDs) can be deposited from colloidal solutions on glassy carbon (GC) electrodes potentiostatically. The immobilization of QDs can be performed at potentials positive and negative from the potential of zero charge (PZC = 0.45 V vs. Ag/AgCl), including the open circuit potential. The surface coverage of QDs depends on the deposition potential and time. The amount of QD layers was determined by following the redox process of cadmium by cyclic voltammetry and chronoamperometry. Additionally, the QD layers were characterized by scanning electrochemical microscopy (SECM) indicating a decrease of the surface conductivity of GC electrodes.

Más información

Título según WOS: ID WOS:000574054600001 Not found in local WOS DB
Título según SCOPUS: Irreversible electrostatic deposition of CdTe quantum dots on glassy carbon electrodes from colloidal solutions
Título de la Revista: Journal of Solid State Electrochemistry
Volumen: 25
Número: 1
Editorial: Springer
Fecha de publicación: 2021
Página final: 140
Idioma: English
DOI:

10.1007/s10008-019-04476-2

Notas: ISI, SCOPUS