Article
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY  (1997)

Preparation and characterization of water-soluble copolymers of N-maleyl glycine with acrylic monomers

Pizarro G.D.C.; Rivas B.L; Geckeler K.E.

Keywords: reactivity, spectroscopy, acid, water, characterization, polymers, solubility, polymerization, synthesis, acids, ratio, resonance, copolymerization, copolymers, nuclear, radical, infrared, monomers, transform, initiators, glycine, method, magnetic, fourier, soluble, Calculations, (chemical), Free, carboxylic, acrylic, Dioxane, Kelen-Tudos, Maleyl, Polyacrylic

Abstract

Two types of copolymers based on N-maleyl glycine with acrylic acid and acrylamide were synthesized. Radical copolymerizations were performed in dioxane at 70°C with AIBN as the initiator. The monomer reactivity ratios were determined using the Kelen-Tüdös method. FT-IR, 1H-NMR, and 13C-NMR spectroscopy as well as elemental analysis were used for the characterization of the copolymers. The comonomer content of the copolymers and the reactivity ratios were calculated from these data.

Más información

Título de la Revista: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
Volumen: 34
Número: 5
Editorial: TAYLOR & FRANCIS INC
Fecha de publicación: 1997
Página de inicio: 855
Página final: 864
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0031141342&partnerID=q2rCbXpz