Highly Pb(II)-selective resin based on crosslinked poly(acrylamido glycolic acid) copolymer

Rivas B.L; Maturana H.A.; Villegas, S; Pereira, E

Abstract

The crosslinked poly(acrylamido glycolic acid) (180-250 ?m) was used in the adsorption/desorption studies. Adsorption rate, capacity of the resin for the selected metal ions, i.e. Cd(III), Zn(II), Hg(II), Pb(II), and Cr(III) were investigated in aqueous media. At different pH values (1.0-5.0) very high adsorption was observed for Pb(II) at pH 3 and 5. The adsorption equilibrium was rapidly achieved in about 5-10 min. However, when the Pb(II) ions competed with Cd(II) (in the case of the adsorption from their binary mixture) the amount of adsorption for Pb(II) decreased. Desorption of Pb(II) was studied by using 1-4M HNO3 and 1-4M HCIO4 High desorption ratios (more than 90%) were achieved in all cases. Adsorption/desorption cycles showed the possibility of repeated use of this resin.

Más información

Título de la Revista: POLYMER BULLETIN
Volumen: 40
Número: 6
Editorial: Springer
Fecha de publicación: 1998
Página de inicio: 721
Página final: 728
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0001681556&partnerID=q2rCbXpz