Sulfuric Acid Promoted Molecular Rearrangement. Applications in Synthesis of Terpenoid Compounds

Banerjee A.; Mendoza, Lisbeth; Briceño Betzabeth; Vera William; Maldonado Alexis; Cabrera Elvia; Arrieche D.; Charles A. Davies

Keywords: sulfuric acid, alcohol, epoxide, ketone, diol

Abstract

The organic compounds containing functional groups like ketone(saturated, unsaturated), alcohol (primary, secondary, tertiary), epoxideetc. undergo rearrangement with sulfuric acid, yielding unexpectedproducts. Alkyl groups attached to the aromatic ring migrate with sulfuric acid from one position to another. Several N-phenyl-hydroxyaminesrearrange with sulfuric acid to amino phenols. The oximes with sulfuricacid furnish substituted amides and lactams.

Más información

Editorial: Nova Science Publishers, Inc.
Fecha de publicación: 2022
Página de inicio: 165
Página final: 173
Idioma: Ingles
DOI:

https://doi.org/10.52305/XEFS4090