Ellipsometric study of multilayer growth and wetting of C2Cl2F4 physisorbed on graphite

Volkmann, U. G.; Mannebach H.; Knorr, K

Keywords: adsorption, growth, film, graphite, isotherms, multilayers, ellipsometry, wetting, Pyrolytic, highly, ordered, (HOPG), Tetrafluorodichloroethane, Chlorofluorocarbons

Abstract

We have used ellipsometry to measure adsorption isotherms of C2Cl2F4 (1,1,2,2-tetrafluoro-1,2-dichloroethane) on a highly ordered pyrolytic graphite (HOPG) substrate in the temperature range from 98 to 185 K. Below the triple point temperature Tt = 179.2 K, the system shows incomplete wetting. Above the bulk triple point, the isotherms show layer-by-layer growth in agreement with the Frenkel-Halsey-Hill model and consistent with complete wetting.

Más información

Título de la Revista: LANGMUIR
Volumen: 14
Número: 17
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 1998
Página de inicio: 4904
Página final: 4907
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0032136685&partnerID=q2rCbXpz