Poly[N-(2-hydroxyethyl)ethyleneimine-co-(1,2,3,6-tetrahydrophthalic anhydride)] by spontaneous copolymerization

Pooley, S.A.; CANESSA, G.S.; Rivas B.L

Abstract

The copolymerization of 1,2,3,6-tetrahydrophthalic anhydride (THPhA) as electrophilic monomer and N-(2-hydroxyethyl)ethyleneiminea as nucleophilic monomer in acetonitrile without initiator was investigated. The copolymers show low incorporation of THPhA in the main chain and preferential incorporation in the side chain by esterification reaction of the hydroxymethyl group. On the basis of the spectroscopic data a copolymer structure is proposed.

Más información

Título de la Revista: MACROMOLECULAR CHEMISTRY AND PHYSICS
Volumen: 199
Número: 10
Editorial: WILEY-V C H VERLAG GMBH
Fecha de publicación: 1998
Página de inicio: 2293
Página final: 2299
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0542395182&partnerID=q2rCbXpz