Influence of the type and the comonomer contents on the mechanical behavior of ethylene/?-olefin copolymers

Simanke A.G.; Galland G.B.; Neto R.B.; Mauler R.S.; Quijada, R

Keywords: olefins, crystal, structure, stress, ray, strain, copolymers, catalysts, composition, methyl, polyethylenes, monomers, organometallics, analysis, effects, X, Hexene, octadecene, Decene, pentene, Octene

Abstract

The influences of the type and concentration of ?-olefin (1-hexene, 1-octene, 1-decene, 1-octadecene, 4-methyl-1-pentene) on the mechanical behavior and crystallinity degree of some ethylene/?-olefin copolymers obtained by metallocene catalysts were studied by means of stress/strain experiments. The crystallinity degree of these copolymers has been determined by X-ray measurements. It has been observed that the copolymers show less resistance to strain as the comonomer content increases and the crystallinity decreases. Most of the studied copolymers exhibit a significant increase in the crystallinity level after the stress/strain experiments.

Más información

Título de la Revista: JOURNAL OF APPLIED POLYMER SCIENCE
Volumen: 74
Número: 5
Editorial: Wiley
Fecha de publicación: 1999
Página de inicio: 1194
Página final: 1200
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0032682171&partnerID=q2rCbXpz