Abstract

The complexes [ Pt{(P(O)(OMe)2)2H}2] and [ PtCl(PPh3){(P(O)(OMe)2) 2H}] react with Tl(acac) in chloroform or with KOH in methanol solution to yield thetrinuclear and binuclear complexes, [ Pt{m -P)O)(OMe)2}4M2] and [ PtCl(PPh3){m -P(O)(OMe)2 }2M] (M = Tl, K), respectively. These derivatives react with (PtMe3)2SO4