Article
Reaction Kinetics and Catalysis Letters  (2001)

Hydroformylation of 1-hexene catalyzed by [Rh(COD)(2-picoline) 2]PF 6 immobilized on poly(4-vinylpyridine) under water gas shift reaction conditions

Pardey A.J.; Brito, J; Fernandez, M. ; RIVAS, A. B.; Ortega M C.; Longo C.; Baricelli. P.J.; Lujano, E; MOYA, S. A.

Keywords: temperature, kinetics, catalysis, polymers, pressure, rhodium, hydroformylation, carbon, monoxide, organic, compounds, Reaction, Hexene, Polyvinylpyridine

Abstract

Reported here is the influence of the reaction conditions variation (1-hexene/rhodium content (S/C) = 16 - 105, temperature (T) = 70 - 110°C and carbon monoxide pressure (P(CO)) = 0.6 - 1.8 atm) on the catalytic hydroformylation of 1-hexene to aldehydes (heptanal and 2-methyl-hexanal) by the rhodium(I) complex, [Rh(COD)(2-picoline) 2]PF 6 (COD = 1,5-cyclooctadiene) immobilized on poly(4-vinylpyridine) in contact with 10 mL of 80% aqueous 2-ethoxyethanol, under water gas shift reaction conditions.

Más información

Título de la Revista: Reaction Kinetics and Catalysis Letters
Volumen: 74
Número: 1
Editorial: Akademiai Kiado
Fecha de publicación: 2001
Página de inicio: 111
Página final: 118
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0035780581&partnerID=q2rCbXpz