Characterization of the Mn-Li ferrite system Li1-0.5xFe1.5x+1-Mn1-xO4 (0.2 ? x ? 1)

Gracia, M; Marco, JF; Gancedo, JR; Gautier, JL; Rios, EI; Menendez, N.; Tornero, J

Abstract

The Mn-Li ferrite system Li1-0.5xFe1.5x+1Mn1-xO4 (x = 1, 0.8, 0.6, 0.4, 0.2) has been studied by means of X-ray diffraction, Mössbauer spectroscopy and Mn K- and Fe K-edge XANES/EXAFS. All the samples show the spinel-related structure with the lattice constant a gradually decreasing between a = 0.8310 nm (x = 1) and a = 0.8301 nm (x = 0.2). Mössbauer and Fe K-edge XANES/EXAFS results have shown that the oxidation state of Fe is +3 and that the fractions of Fe3+ ions occupying the octahedral and tetrahedral sublattices do not change significantly along the series. Mössbauer data recorded under applied magnetic field indicate the existence in the Mn-containing samples of canted spin structures for the Fe3+ ions on both the tetrahedral and octahedral sites, the canting angle being larger for the octahedral sublattice. Mn K-edge XANES and EXAFS have shown Mn to be present as Mn3+ and Mn4+ and to occupy only octahedral sites. The XANES/EXAFS results have also shown that the Mn4+/Mn3+ ratio increases with increasing Li/Mn content. The results indicate that as the extent of Li/Mn insertion increases the new inserted Li+ ions occupy tetrahedral sites and that some of the Li+ ions initially occupying octahedral sites are also driven into tetrahedral positions.

Más información

Título según WOS: Characterization of the Mn-Li ferrite system Li1-0.5xFe1.5x+1-Mn1-xO4 (0.2 <= x <= 1)
Título según SCOPUS: Characterization of the Mn-Li ferrite system Li1-0.5xFe1.5x+1-Mn1-xO4 (0.2 ? x ? 1)
Título de la Revista: JOURNAL OF MATERIALS CHEMISTRY
Volumen: 13
Número: 4
Editorial: RSC
Fecha de publicación: 2003
Página de inicio: 844
Página final: 851
Idioma: English
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0037386644&partnerID=q2rCbXpz
DOI:

10.1039/b212474b

Notas: ISI, SCOPUS