Portal del Investigador
Regioselective oxidative fragmentation of drimanic terpene alcohols: Ashort, easy and efficient access to natural and synthetic 11-nordrimaneterpenederivatives
Keywords: oxidation, fragmentation, aerobic, metabolism, stereochemistry, drug, article, chromium, analysis, drimenol, 7, 1, 3, derivative, Reaction, 2, 1h, unclassified, oxo, 4h, one, terpene, diol, naphthalen, 11,12, Pyridinium, trimethyl, tetramethyl, carbaldehyde, hexahydro, 2,5,5,8a, 4a,5,6,7,8,8a, 3,4a,8,8, 5,5,8a, 1,4,4a,5,6,7,8,8a, octahydronaphthalene, 3,4,4a,5,6,7,8,8a, drimene, chlorochromate
Abstract
Using selective Cr(VI) oxidations with Jones reagent and PCC, a regioselective and direct access to different oxygenated 11-nordrimane skeletons was achieved, in good overall yield, starting from naturally occurring drimane terpenes.
Más información
| Título según SCOPUS: | Regioselective oxidative fragmentation of drimanic terpene alcohols: Ashort, easy and efficient access to natural and synthetic 11-nordrimaneterpenederivatives |
| Título de la Revista: | ARKIVOC |
| Volumen: | 2003 |
| Número: | 10 |
| Editorial: | ARKAT USA INC |
| Fecha de publicación: | 2003 |
| Página de inicio: | 169 |
| Página final: | 177 |
| Idioma: | English |
| URL: | http://www.scopus.com/inward/record.url?eid=2-s2.0-3242666056&partnerID=q2rCbXpz |
| Notas: | SCOPUS |