Article
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY  (2004)

Comparative study of two chemically isostructural polymers: [Cu 2(VO2)-(HPO4)2(NO 3)(bpy)2]·2H2O/H3PO 4 (bpy is 2,2?-bipyridine)

Moreno Y.; Vega A.; Spodine, E.; Ushak, E; Baggio R.

Keywords: copper, dynamics, complexes, coordination, water, crystal, polymers, solutions, ion, molecules, crystallization, structure, composition, bonds, exchange, interactions, molecular, organometallics, compounds, chemical, inorganic, Interchain

Abstract

The crystal structure of copper compound, [Cu2(VO 2)(HPO4)2 (NO3)(bpy)2].X was studied. These chemically isostructural systems were obtained by hydrothermal methods, which differ in the solvate molecules stabilizing the structures. The compound were stabilized by different solvates, two crystallization water molecules in (I) and a phosphoric acid molecule in (II). This provides the main structural differences through the diversity of interchain in which they serve as bridges.

Más información

Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volumen: 60
Número: 10
Editorial: WILEY-BLACKWELL
Fecha de publicación: 2004
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-8344270206&partnerID=q2rCbXpz