Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION  (2009)

Nickel ?-Keto-?-diimine initiators for olefin polymerization

Azoulay J.D.; Ohtaki, H; Wu G.; Bazan G.C.; Rojas R.S.; Serrano A.V.; Galland G.B.

Keywords: kinetics, catalysis, olefins, electron, ligands, polymers, polymerization, metal, acids, recovery, alloys, ethylene, sites, nickel, molecular, monomers, diimine, densities, combinations, effects, weights, substituent, olefin, chemical, Reaction, reactions, High, Catalytic, Homogeneous, Lewis, polymerizations

Abstract

(Figure Presented) A new ligand-metal combination (see picture, Ni green, Br brown, N blue, O red, C gray) was designed to be cationic and to benefit from removal of electron density by the action of a Lewis acid on the ligand framework. In the presence of various activators, the resulting catalytic site is highly active for ethylene polymerization and capable of polymerizing ?-olefins to high molecular weights. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Más información

Título de la Revista: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volumen: 48
Número: 6
Editorial: WILEY-V C H VERLAG GMBH
Fecha de publicación: 2009
Página de inicio: 1089
Página final: 1092
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-59049098693&partnerID=q2rCbXpz