Article SCIELO
BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA  (2001)

FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

Manzur, Carolina; Fuentealba, Mauricio; Carrillo, David; Boys, Daphne; Hamon, Jean-Rene

Abstract

The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalline and molecular structure has been determined and consists of two iron(II) sandwiches of the type [(h 5-Cp)Fe(h 6-arene)]+ and [(h 5-C5H4)Fe(h 5-Cp)], in anti position one with respect to the other, and linked by a zigzag hydrazonic spacer

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Título según SCIELO: FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
Título de la Revista: BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
Volumen: 46
Número: 4
Editorial: Sociedad Chilena de Química
Fecha de publicación: 2001
Página de inicio: 409
Página final: 413
Idioma: en
URL: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004&lng=en&nrm=iso&tlng=en
DOI:

10.4067/S0366-16442001000400004
Notas: SCIELO