Article ISI SCOPUS
DALTON TRANSACTIONS  (2012)

Synthesis of [(pi-cyano-P-nacnac)Cp] and [(pi-cyano-nacnac)Cp]-zirconium complexes, and their remote activation for ethylene polymerization

Rojas R.S.; Cabrera A.R.; Peoples B.C.; Spannhoff K.; Valderrama M.; Frohlich, R; Kehr, G; Erker, G

Abstract

In this contribution the synthesis and characterization of two distinct, yet similar, zirconium complexes, [(π-P-nacnac-CN)Cp] and [(π-nacnac-CN)Cp] zirconium dichloride were discussed. In addition to the complexes, Lewis acid adducts [B(C 6F 5) 3] of the complexes were isolated and characterized as well. It was found that while structurally similar, the complexes behave distinctly upon adduct formation and in their ethylene polymerizations. © 2012 The Royal Society of Chemistry.

Más información

Título según WOS: Synthesis of [(pi-cyano-P-nacnac)Cp] and [(pi-cyano-nacnac)Cp]-zirconium complexes, and their remote activation for ethylene polymerization
Título según SCOPUS: Synthesis of [(?-cyano-P-nacnac)Cp] and [(?-cyano-nacnac)Cp]- zirconium complexes, and their remote activation for ethylene polymerization
Título de la Revista: DALTON TRANSACTIONS
Volumen: 41
Número: 4
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2012
Página de inicio: 1243
Página final: 1251
Idioma: English
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-84855858790&partnerID=40&md5=fdd64dd0921e986dee1293bb941a91cd
DOI:

10.1039/c1dt11261a
Notas: ISI, SCOPUS