Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers

Muñoz-Lara, Francisco J.; Gaspar, Ana B.; Aravena, Daniel; Ruiz, Eliseo; Muñoz, M. Carmen; Ohba, Masaaki; Ohtani, Ryo; Kitagawa, Susumu; Real, José A.

Abstract

Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN) 4]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature. © 2012 The Royal Society of Chemistry.

Más información

Título según SCOPUS: Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers
Título de la Revista: CHEMICAL COMMUNICATIONS
Volumen: 48
Número: 39
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2012
Página de inicio: 4686
Página final: 4688
Idioma: English
DOI:

10.1039/c2cc31048a

Notas: SCOPUS - SCOPUS