Abstract

Droplets and bubbles protected by armors of particles have found vast applications in encapsulation, stabilization of emulsions and foams, or flotation processes. The liquid phase stores capillary energy, while concurrently the solid contacts of the granular network induce friction and energy dissipation, leading to hybrid interfaces of combined properties. By means of nonintrusive tensiometric methods and structural measurements, we distinguish three surface phases of increasing rigidity during the evaporation of armored droplets. The emergence of surface rigidity is reminiscent of jamming of granular matter, but it occurs differently since it is marked by a step by step hardening under surface compression. These results show that the concept of the effective surface tension remains useful only below the first jamming transition. Beyond this point, the surface stresses become anisotropic.