Responsivity-based criterion for accurate calibration of FTIR emission spectra: theoretical development and bandwidth estimation

Rowe, Penny M.; Neshyba, Steven P.; Walden, Von P.

Abstract

An analytical expression for the variance of the radiance measured by Fourier-transform infrared (FTIR) emission spectrometers exists only in the limit of low noise. Outside this limit, the variance needs to be calculated numerically. In addition, a criterion for low noise is needed to identify properly calibrated radiances and optimize the instrument bandwidth. In this work, the variance and the magnitude of a noise-dependent spectral bias are calculated as a function of the system responsivity (r) and the noise level in its estimate (sigma(r)). The criterion sigma(r)/r < 0.3, applied to downwelling and upwelling FTIR emission spectra, shows that the instrument bandwidth is specified properly for one instrument but needs to be restricted for another. (C)2011 Optical Society of America

Más información

Título según WOS: Responsivity-based criterion for accurate calibration of FTIR emission spectra: theoretical development and bandwidth estimation
Título de la Revista: OPTICS EXPRESS
Volumen: 19
Número: 6
Editorial: WASHINGTON
Fecha de publicación: 2011
Página de inicio: 5451
Página final: 5463
Idioma: English
URL: http://www.opticsinfobase.org/abstract.cfm?URI=oe-19-6-5451
DOI:

10.1364/OE.19.005451

Notas: ISI