A one step functionalization, coordination of N3P 3Cl6 using [CpFe(dppe)SC6H4OH]

Díaz, C.; Spodine, E.; Moreno Y.; Carrasco, E

Keywords: Cyclophosphazenes; Iron, thiolates; Magnetic properties; Sulphur ligands

Abstract

The new iron-thiolate complex [CpFe(dppe)SC6H 4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6H 4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussed.

Más información

Título según SCOPUS: A one step functionalization, coordination of N3P 3Cl6 using [CpFe(dppe)SC6H4OH]
Título de la Revista: JOURNAL OF THE CHILEAN CHEMICAL SOCIETY
Volumen: 49
Número: 3
Editorial: 2013
Fecha de publicación: 2004
Página de inicio: 205
Página final: 208
Idioma: English
Notas: SCOPUS