The preparation of PbO2 coatings on reticulated vitreous carbon for the electro-oxidation of organic pollutants

Recio, FJ; Herrasti, P; Sirés I.; Kulak, AN; Bavykin, DV; Ponce-De-León C.; Walsh, FC

Keywords: electrodeposition, electrochemical oxidation, Lead dioxide, Methanesulfonic acid, Reticulated vitreous carbon

Abstract

The preparation of PbO2 coatings on reticulated vitreous carbon (RVC) has been carried out at constant current from electrolytic baths containing aqueous Pb(II) and methanesulfonic acid (MSA, CH3SO3H). The morphological and structural analysis of the RVC/PbO2 deposits carried out by scanning electron microscopy (SEM) and X-ray diffraction revealed that a thick (100 mu m), homogeneous, nanostructured beta-PbO2 film can be successfully formed. As a result, three-dimensional beta-PbO2 structures were obtained, being particularly interesting for their use as anodes in wastewater treatment. The high oxidation ability of these anodes has been verified by the electro-oxidation of Methyl Orange aqueous solutions. Quick decolourisation was achieved, with total colour removal in less than 60 min at 600 mA due to the production of large amounts of reactive (OH)-O-center dot radicals from the oxidation of water at high anodic potentials. The progressive mineralisation of the solutions was also ascertained from the total organic carbon (TOC) removal, which was much quicker at a higher applied current. All the coated RVC electrodes exhibited excellent long-term stability and remained unaltered after prolonged electrolyses. In addition, novel PbO2 composite coatings were prepared in the presence of hydrothermally synthesized titanate nanotubes (TiNT). The SEM images showed the presence of TiNT agglomerates along the PbO2 surface, which led to higher anodic current in the cyclic voltammetries carried out with Methyl Orange solutions. It is suggested that TiNT favour the adsorption of the organic molecules, facilitating the contact with the (OH)-O-center dot radicals and thus accelerating the electro-oxidation process. This was confirmed by the faster TOC removal compared to that yielded by the RVC/PbO2, being 45% instead of 24% at 120 min. (C) 2011 Elsevier Ltd. All rights reserved.

Más información

Título según WOS: The preparation of PbO2 coatings on reticulated vitreous carbon for the electro-oxidation of organic pollutants
Título de la Revista: ELECTROCHIMICA ACTA
Volumen: 56
Número: 14
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2011
Página de inicio: 5158
Página final: 5165
Idioma: English
DOI:

10.1016/j.electacta.2011.03.054

Notas: ISI