Mechanism of corrosion of cast iron covered by aged corrosion products: Application of electrochemical impedance spectrometry

Sancy, M.; Gourbeyre, Y; Sutter, EMM; Tribollet, B

Keywords: iron, eis, oxygen reduction, interfaces, raman spectroscopy

Abstract

This work focuses on the corrosion of cast iron in a drinking water network. The study is performed in water and in a sandy soil saturated with the same water. In the presence of corrosion products, the inner wall surface shows a lower corrosion rate than the external wall. In the two media, impedance diagrams are described by a high-frequency loop characteristic of a protective corrosion layer and a diffusion impedance loop at low frequencies associated with oxygen diffusion. Different models involving mass transfer through a porous layer are suggested for the inner and the external corrosion layers. (C) 2009 Elsevier Ltd. All rights reserved.

Más información

Título según WOS: Mechanism of corrosion of cast iron covered by aged corrosion products: Application of electrochemical impedance spectrometry
Título de la Revista: CORROSION SCIENCE
Volumen: 52
Número: 4
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2010
Página de inicio: 1222
Página final: 1227
Idioma: English
DOI:

10.1016/j.corsci.2009.12.026

Notas: ISI