Article
Inorganic Chemistry  (2008)

Structure and Magnetic properties of the hybrid System copper (II) μ2-2,2’- Bypiridine-3-carboxylate-N,N’: O-μ2-phosphate- O,O

Y. Moreno; G. Cárdenas; A. Tissot; O. Peña; J.-Y. Pivan; R. Baggio

Abstract

The title compound [Cu(PO4H2)(C11H7N2O2)]n presents antiferromagnetic behavior. It has a polymeric one-dimensional structure in which the elemental links are tetranuclear units and the doubly protonated phosphates and the bipyridinemonocarboxylates act in a bridging mode. The magnetic behavior is described using an alternating chain model, with J = −3.32 cm−1, α = 0.7, and g = 2.05

Más información

Título de la Revista: Inorganic Chemistry
Volumen: 47
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2008
Página de inicio: 2334
Página final: 2337
DOI:

DOI: 10.1021/ic701137d
Notas: ISI, DOI: 10.1021/ic701137d