Abstract

The collisional, superelastic encounters at ultralow energies of Li+ with D2 are computed using the exact coupled-channel dynamics, and using an ab initio potential energy surface discussed in earlier work. The changes in the target rovibrational structure due to the isotopic substitution, and in its rovibrational wave functions, are seen to have a marked effect, under the collision conditions of vanishing relative energy, on the corresponding dynamical attributes, allowing one to make specific predictions on the possible use of isotopic variants in cold trap processes.