Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine)

Pardey, AJ; Fernandez, M. ; Alvarez J.; Ortega, MC; Canestrari, M; Longo C.; Aguirre P.; Moya, SA; Lujano, E; Baricelli, PJ

Abstract

Kinetic studies of the water gas shift reaction have been carried AE t in the presence of [Rh(COD) (4-picoline)(2)] PF6, (COD = 1,5-cyclooctadiene) as catalyst, immobilized on poly(4-vinylpyridine) 2% cross linked with divinylbenzene in contact with a mixture of 80% aqueous 2-ethoxyethanol. The rhodium complex was anchored to the pyridine groups of the organic polymer. Analyses of kinetic results show a first order dependence on carbon monoxide pressure, a nonlinear dependence on rhodium total concentration and a segmented Arrhenius plot. These data are discussed in terms of a possible mechanism.

Más información

Título según WOS: Kinetics of the water gas shift reaction catalyzed by [Rh(COD)(4-picoline)(2)]PF6 immobilized on poly(4-vinylpyridine)
Título según SCIELO: Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine)
Título de la Revista: BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
Volumen: 45
Número: 3
Editorial: Sociedad Chilena de Química
Fecha de publicación: 2000
Página de inicio: 347
Página final: 354
Idioma: English
DOI:

10.4067/S0366-16442000000300003

Notas: ISI, SCIELO