Bis(acetonitrile-N)(o-benzoquinone diimine-N,N ')-trans-bis(triphenylphosphine-P)ruthenium(II) bis(hexafluorophosphate) methanol solvate

Venegas-Yazigi, D; Mirza, H; Lever, ABP; Lough, AJ; Costamagna J; Latorre, RN

Abstract

The title complex, [Ru(C2H3N)(2)(C6H6N2)(C18H15P)(2)](PF6)(2). CH4O, is the third of a series of ruthenium complexes containing two triphenylphosphine groups in a trans arrangement, o-benzoquinone diimine and two other non-redox active ligands to been characterized. The effect of electron donor-acceptor properties of the two non-redox active ligands does not change the quinone arrangement for the o-benzoquinone diimine ligand, as can be seen from the bond distances of the quinone ring. The asymmetric unit contains half a molecule of complex cation (on a twofold rotation axis), one hexafluorophosphate anion and half a molecule of methanol in a general position close to a twofold rotation axis.

Más información

Título según WOS: Bis(acetonitrile-N)(o-benzoquinone diimine-N,N ')-trans-bis(triphenylphosphine-P)ruthenium(II) bis(hexafluorophosphate) methanol solvate
Título de la Revista: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volumen: 56
Editorial: WILEY-BLACKWELL
Fecha de publicación: 2000
Página de inicio: E281
Página final: E282
Idioma: English
URL: http://scripts.iucr.org/cgi-bin/paper?S0108270100007654
DOI:

10.1107/S0108270100007654

Notas: ISI